To startup Emacs maximised, add to your init file:
;; Start maximised (cross-platf)
(add-hook 'window-setup-hook 'toggle-frame-maximized t)
In case you want to go full screen or, as they say now, distraction free mode:
;; Start fullscreen (cross-platf)
(add-hook 'window-setup-hook 'toggle-frame-fullscreen t)
(add-hook 'window-setup-hook 'toggle-frame-fullscreen t)
NOTE: This works in Windows too.