The following works because you can write table formulas with elisp code. Notice the '
(quote) before the s-exp.
| # | B | C |
|---+---+---|
| 1 | 2 | 3 |
| 1 | 2 | 3 |
#+TBLFM: @1$1='(format "#")
EvaluableEvaluate (info "(org) Formula syntax for Lisp")
for more information.