Add the following to your init file:
(setq org-latex-toc-command "\\tableofcontents \\clearpage")
Explanation:
The variable org-latex-toc-command
normally is set to the value "\\tableofcontents"
and its value is emitted by the LaTeX exporter into the output TeX file at the place where the TOC is to be placed (normally right after the \begin{document}
in the TeX file):
\begin{document}
\tableofcontents
...
When the TeX file is processed to produce the PDF output file, the LaTeX processor expands the \tablecontents
macro to the full TOC.
By modifying the value of org-latex-toc-command
, the LaTeX exporter is made to emit the modified string, so the TeX file looks liks this:
\begin{document}
\tableofcontents \clearpage
...
When the modified TeX file is processed by the LaTeX processor, after \tableofcontents
is expanded to the full TOC, the \clearpage
macro causes the page to be emitted immediately, leaving the rest of it blank.
Note BTW, that in an emacs string like "\\foo"
, the first backslash "escapes" the second, so that one backslash is part of the string. More about such escape sequences can be found in the Emacs documentation, e.g. here and here.