If you want all tables to be always left-aligned, then setting org-latex-tables-centered
as @gigiair's answer suggests is the right way to go: you customize it once and never worry about it again.
If you want to change the centering behavior only for a single file, then the way to do it is to use the #+BIND
mechanism. Add the following line to the top of your file:
#+BIND: org-latex-tables-centered nil
That will set the local value of org-latex-tables-centered
to nil during export only.
In order for this to work however, you will have to enable the BIND mechanism by setting (or customizing) the variable org-export-allow-bind-keywords
to t
. I find the BIND mechanism useful, so I set it permanently.
Finally, if you want to change the centering of a single table, you can set an attribute for that table only:
#+NAME: cubes
#+ATTR_LATEX: :center nil
| a | a^{3} |
|----+-------|
| 1 | 1 |
| 2 | 8 |
...