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Thanks to d125q's comments, I solved the issue. It was twofold: First and foremost, unicode-math is a package which only works with XeTeX or LuaTeX, but org by default compiles with LaTeX. This is why you need the preview images to be generated by XeTeX or LuaTeX. This is my configuration: (setq org-preview-latex-process-alist '((dvipng :programs ...

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